Synergistic dual activation catalysis by palladium nanoparticles for epoxide ring opening with phenols.
نویسندگان
چکیده
Synergistic dual activation catalysis has been devised for epoxide phenolysis wherein palladium nanoparticles induce electrophilic activation via coordination with the epoxide oxygen followed by nucleophilic activation through anion-π interaction with the aromatic ring of the phenol, and water (reaction medium) also renders assistance through 'epoxide-phenol' dual activation.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 52 شماره
صفحات -
تاریخ انتشار 2013